| HS Code | 679234 |
| Product Name | Fast Scarlet BBC-Y |
| Color Index Name | C.I. Pigment Red 48:2 |
| Color Index Number | C.I. 15865:2 |
| Chemical Class | Monoazo calcium lake |
| Cas Number | 2814-77-9 |
| Appearance | Red powder |
| Color Shade | Yellowish red |
| Oil Absorption | 35-45 g/100 g |
| Specific Gravity | 1.6-1.8 g/cm3 |
| Moisture Content | ≤1.0% |
| Water Soluble Matter | ≤1.0% |
| Ph Value | 7-9 |
| Lightfastness | 4-5 |
| Heat Resistance | 180°C |
| Primary Applications | Inks, paints, plastics |
As an accredited Fast Scarlet BBC-Y factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Fast Scarlet BBC-Y is packaged in 25 kg net polyethylene-lined paper bags, securely palletized for industrial transport and storage. |
| Container Loading (20′ FCL) | Fast Scarlet BBC-Y is securely packed and loaded into a clean, dry 20′ FCL container for safe transport. |
| Shipping | Fast Scarlet BBC-Y should be shipped in sealed, properly labeled containers using suitable outer packaging. Protect from moisture, heat, and direct sunlight; secure packages to prevent leakage. Avoid contact with incompatible oxidizers. Follow all applicable local, national, and international transport regulations, current SDS requirements, and maintain shipping documentation. |
| Storage | Store Fast Scarlet BBC-Y in a cool, dry, well-ventilated area, protected from direct sunlight, heat, moisture, and ignition sources. Keep containers tightly closed, correctly labeled, and off the floor. Separate from strong oxidizers, acids, and reducing agents. Avoid dust generation and use suitable containment and spill precautions. Do not store with food or feed. Follow the SDS and local regulations. |
| Shelf Life | Typically 24 months when stored unopened in a cool, dry, well-ventilated area away from light and moisture. |
In sheetfed offset ink manufacturing, Fast Scarlet BBC-Y is dispersed into a high-viscosity alkyd-linseed varnish at 15–20 wt% pigment loading on a three-roll mill with roll temperature 35–45°C and hydraulic roll pressure 0.6–1.2 MPa. The monoazo barium salt structure provides solvent insolubility and high tinctorial strength. The critical control point is grind fineness: a Hegman gauge reading below 5 µm according to ISO 1524 is required to prevent plate dot bridging. The resulting paste is tack-adjusted to 8–12 inkometer units at 32°C using a Thwing-Albert instrument. Fountain solution interaction is evaluated by a 30-min emulsification test; at pigment addition above 2.0 wt% of a 40% solids varnish, water uptake may increase by 15–25%. Proofing on gloss-coated board at an ink film weight of 1.2–1.5 g/m² is compared against ISO 2846-1 colorimetry. Finished products include coated paper packaging, magazine covers, and point-of-sale card stock.
UV-curable sheetfed inks impose an additional constraint. Fast Scarlet BBC-Y is milled into a mixture of urethane acrylate and tripropylene glycol diacrylate at the same pigment loading, but the photoinitiator package must be limited to 6–9 wt% because the pigment absorption tail can compete with acylphosphine oxide at 380–420 nm. Cure response is checked by a belt-speed test under a 120 W/cm mercury arc lamp; at film weights above 1.5 g/m² the ink may require a second lamp pass. The end-use requirement is through-cure without surface tack on non-absorbent substrates.
Water-based flexographic ink production uses a separate dispersion path. Fast Scarlet BBC-Y is pre-dispersed in water at 35–40 wt% pigment content with a styrene-acrylic dispersing resin and a silicone-free defoamer, then milled in a horizontal bead mill charged with 0.8–1.0 mm yttria-stabilized zirconia beads. Chamber residence time is kept between 8–15 min. The final ink is let down to pH 8.8–9.4 and viscosity 35–45 s on a DIN 4 cup at 25°C. Glycol ether addition is limited to 2–4 wt% to control foam without exceeding substrate solvent retention. Printing on white-top corrugated linerboard at 150–200 m/min requires forced-air drying at 80–100°C for 2–4 s before rewinding. End uses include shipping containers, paper sacks, and beverage carrier board. Compliance for heavy-metal release is verified by EN 71-3:2019, while the ink supplier maintains REACH registration for the pigment. PH above 9.5 is avoided because prolonged alkaline exposure can hydrolyze the barium salt surface and drift ink viscosity.
In polyolefin masterbatch production, Fast Scarlet BBC-Y is compounded at 25–40 wt% loading on a co-rotating twin-screw extruder with L/D 40:1 and screw speed 400–600 rpm. The carrier is LDPE or EVA with melt temperature 190–215°C; PP homopolymer processing above 220°C is not recommended because the yellow-shade barium salt approaches its heat stability limit. Vacuum venting at −0.08 MPa removes adsorbed moisture before the die. Single-screw letdown at 0.1–0.5 wt% in blow moulding is monitored by filter pressure value through a 20 µm melt filter; typical FPV increase is 0.8–1.5 bar/g after 200 g throughput. End products are LDPE carrier bags, EVA foam sheet, and non-food caps. Migration testing according to EN 71-3:2019 and CONEG heavy-metal limits is mandatory; the material is not recommended for direct food-contact articles without a functional barrier.
| Letdown concentration (wt%) | Blow moulding melt temperature (°C) | EN 71-3 migration class | Processing note |
|---|---|---|---|
| 0.1 | 200 | Pass under limit values | Filter pressure increase below 0.7 bar/g |
| 0.25 | 205 | Pass under limit values | Color strength stable after 4 h hold |
| 0.5 | 210 | Pass under limit values | Increased risk of pigment agglomeration without dispersant |
In flexible PVC calendering, Fast Scarlet BBC-Y is incorporated at 0.3–1.0 phr in a pre-mix with DOP or DINP plasticizer, calcium/zinc stabilizer, and epoxidized soybean oil. The pre-mix is heated in a planetary mixer at 90–110°C, then fluxed on a two-roll mill at 150–165°C before transfer to a four-roll calender. The melt residence time above 180°C must not exceed 20–25 min; beyond this window the yellow-shade red may darken and opacity decreases by 8–12% measured as CIE ΔL*. Calendered sheet of 0.8–2.0 mm thickness is used for stationery covers, inflatable membrane substrates, and automotive interior trim. Contact bleed against a white plasticized PVC counterpart is evaluated by ISO 105-A05. Barium extractable values are checked against EN 71-3 limits where the end article falls within toy or childcare scope.
Powder coating production subjects Fast Scarlet BBC-Y to a twin-screw extruder pre-mix at 70–90°C and 300–500 rpm, followed by pin milling to D50 18–28 µm. The pigment is loaded at 0.5–2.0 wt% of total powder coating weight. The main processing conflict is curing oven color shift: at 200°C for 10 min, the cured coating should show ΔE*ab below 1.5 against an underbaked control. Bonded metallic systems impose an additional thermal bonding step at 60–70°C where pigment aggregates can shift particle size distribution and alter metallic effect. End uses include architectural interior trim, appliance top coats, and non-exposed automotive wheel coatings. For exterior powder coatings, the pigment is excluded where ISO 11341 xenon-arc exposure rating of level 4 or higher after 1000 h is specified; published data for this specific configuration is limited.
In sulfur-cured rubber compounds, Fast Scarlet BBC-Y is added at 1.0–2.5 phr on a two-roll mill at 40–60°C. The pigment does not participate in crosslinking, but its surface can adsorb accelerator fragments; at ≤2.0 phr with a CBS/sulfur ratio of 0.4/1.6, the cure rate index according to ISO 3417 remains essentially unchanged. Above 2.5 phr, tensile strength measured by ISO 37-2 may decrease by 5–10% because of pigment agglomeration acting as a local stress concentration. Discoloration testing according to ASTM D1148 is required for light-exposed EPDM and SBR articles; Fast Scarlet BBC-Y is formulated only in high-chroma, non-white compounds. Finished products include red rubber mats, automotive sealing profiles, and industrial hoses. PAH migration for long-term skin contact articles must be evaluated under REACH Annex XVII entry 50, with the supplier datasheet consulted for individual PAH concentrations.
Textile pigment printing converts the pigment into an aqueous suspension containing 10–20 wt% Fast Scarlet BBC-Y, 3–6 wt% acrylic binder, 1–2 wt% associative thickener, and 0.5–1.0 wt% ammonium polyacrylate dispersant. The paste is applied through rotary screens with 125–150 mesh/cm or flat screens with 43–62 threads/cm, followed by drying at 110–130°C and curing at 150°C for 2–3 min. Wet crockfastness must meet ISO 105-X12 grade 3–4; dry crockfastness grade 4–5 is typical at a binder-to-pigment ratio of 1.5:1. The printed fabric is tested for formaldehyde according to ISO 14184-1. Barium extractable values are checked against OEKO-TEX Standard 100 Class II limits; the pigment is excluded from Class I infant use if the barium extractable value exceeds the standard limit.
Solvent-based nitrocellulose-polyurethane gravure inks incorporate Fast Scarlet BBC-Y at 8–12 wt% of liquid ink after pin-mill dispersion at 35–50°C. The solvent blend is ethyl acetate/isopropanol/propylene glycol monomethyl ether at 70:20:10 by weight; viscosity is adjusted to 18–25 s on a DIN 4 cup at 23°C. Printing on metallized BOPP or PET at 100–250 m/min uses a laser-engraved cylinder with cell depth 30–40 µm. Solvent resistance of the dried film is measured by MEK double rubs according to ASTM D5402, requiring ≥50 rubs without visible pigment transfer. Residual solvent content must remain below 5 mg/m² by GC headspace for flexible food packaging; the pigment is placed only in non-food-contact layers unless a functional barrier is validated under Commission Regulation (EU) No 10/2011. End products include snack packaging laminates, shrink sleeves, and wrappers.
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Fast Scarlet BBC-Y is supplied as a yellow-shade β-naphthol azo lake pigment, with supplier documentation cross-referencing the grade to C.I. Pigment Red 53:1 chemistry. The suffix -Y denotes a yellow-shade adjustment in the commercial series; it does not encode strength or particle size. Bulk density, oil absorption, and sieve residue values are lot-dependent and should be read against the certificate of analysis. The grade differs from blue-shade scarlet lakes in hue angle and in tinctorial response under high shear; it differs from non-laked disazo scarlets in solvent bleed resistance and thermal stability. Published data for this specific configuration is limited; the parameters below are representative of comparable barium lake grades and require verification for the -Y lot.
| Property | Method | Representative value |
|---|---|---|
| Density | ISO 787-23 | 1.60–1.70 g/cm³ |
| Oil absorption | ISO 787-5 | 40–50 g/100 g |
| pH of aqueous extract | ISO 787-9 | 6.0–8.0 |
| Volatile matter at 105 °C | ISO 787-2 | ≤2.0 % |
| Residue on 45 µm sieve | ISO 787-7 | ≤0.5 % |
| Relative tinting strength | ISO 787-24 | 100–105 % |
| Heat stability in LDPE | DIN EN 12877-1 | 180–200 °C |
| Light fastness, full shade, Blue Wool | ISO 105-B02 | 4–5 |
The relatively high oil absorption of 40–50 g/100 g indicates that formulation viscosity will rise disproportionately when pigment loading exceeds 20 wt% in solventborne paste. Sieve residue is measured after wet sieving; values above 0.5 % correlate with visible specks in 20 µm drawdowns. The pH of aqueous extract should be monitored because acidic extract values below 6.0 can destabilize resinated letdown vehicles, while alkaline values above 8.0 can accelerate barium lake dissociation. Heat stability data derived by DIN EN 12877-1 in LDPE are processing-cell dependent; the 180–200 °C range is a screening window, not a substitution for trial extrusion at production scale.
During twin-screw extrusion of polyolefin masterbatch on a 40:1 L/D co-rotating machine with 12-zone temperature settings from 180 °C to 220 °C, the grade exhibits no abrupt plate-out when screw speed is held between 600 min⁻¹ and 900 min⁻¹ and feed rate is adjusted to maintain 55–65 % torque. Pre-drying is required at relative humidity above 60 %; moisture above 0.3 % in the pigment feed can generate hydrolytic degradation products that shift melt pH and cause screen-pack pressure rise. In comparison with C.I. Pigment Red 48:2, the BBC-Y grade requires a higher letdown ratio to achieve equal tinctorial strength in a 1:100 TiO₂ reduction; the difference is attributed to oil absorption and particle size distribution. The processing window is narrow in polypropylene: at zone temperatures above 230 °C, yellow-shade azo lakes begin thermal discoloration; at temperatures below 180 °C, incomplete dispersion yields visible agglomerates on 20 µm cast film. Dispersion quality should be checked by optical microscopy at 100× or by pressure-rise test over a 200 µm screen pack. A pressure increase of more than 25 % over 30 min at constant screw speed indicates agglomerate accumulation and requires either feed-rate reduction or pre-dispersion modification.
Batch-to-batch variance is most visible in melt filtration efficiency. On a single-screw extruder equipped with a 200 µm mesh screen, filter pressure index measurements taken at 10 min intervals after startup show that lots with sieve residue above 0.3 % generate pressure-rise slopes exceeding 0.4 bar/min. Such lots are unsuitable for high-concentration masterbatch because screen-pack change frequency rises from approximately 8 h to 3 h. Operators should request the ISO 787-7 residue value and the optical microscopy count of particles above 10 µm when qualifying a new lot.
Sheetfed offset ink at 20 wt% pigment loading requires three-roll mill passes at 3 bar hydraulic pressure and 25 °C roller temperature to produce a Hegman grind of 7–8 on the Hegman scale according to ISO 1524. The rheological response is shear-thinning; a tack value of 8–12 at 400 rpm on a Tackoscope at 32 °C is typical when the vehicle contains 30–35 % high-boiling mineral oil. The product's oil absorption restricts direct extension; formulations above 22 wt% pigment may require polyfunctional oligomer addition to prevent roller caking. Compared with a blue-shade barium lithol rubine, the yellow-shade BBC-Y grade develops lower tack loss after water pickup but greater sensitivity to fountain solution pH; the difference is measurable after 120 s in a Duke emulsification test. This pH sensitivity imposes an operational boundary: fountain solution pH must be controlled between 4.5 and 5.5, and ink duct temperature must remain below 35 °C; increases above that point raise tack loss from emulsification and produce mottle on coated stock. The addition of amine-based pH adjusters is not recommended; alkaline species accelerate metal lake dissociation and shift hue.
In solvent-based NC/PU gravure systems, Fast Scarlet BBC-Y shows acceptable resinated letdown stability when the binder is a nitrocellulose/polyurethane blend with 15–20 % ethyl acetate. After 24 h at 25 °C, return viscosity measured on a cone-and-plate viscometer at 100 s⁻¹ should remain below a 10 % increase threshold if the pigment is predispersed in 12–15 % alcohol-rich solvent with a resinated pigment-to-binder ratio of 1:1.2. If flocculation occurs, the ink exhibits viscosity drift and colour strength loss after drawdown; the condition is detected by a 3 µm NPIRI grind gauge. The product differs from C.I. Pigment Red 57:1 in lower solvent bleed in toluene-based packings; however, published data for this specific configuration is limited. Avoid combination with amine-based dispersants in ethyl acetate-rich systems; such additives can strip barium from the lake and produce a pH rise above 8.5, leading to sedimentation.
Sulphur-cured EPDM and SBR compounds accept the product as a non-reinforcing organic colorant. The barium lake does not interfere with thiazole/sulphenamide cure systems at loadings below 5 phr; at higher loadings, the pigment releases soluble barium ions that can activate acidic accelerators and shorten scorch time. Oscillating disc rheometer data at 160 °C, 1° arc, and 30 min test duration show no significant change in minimum torque when the pigment is added at 2 phr. Bloom resistance in SBR vulcanizates is rated visually after 72 h at 70 °C and 95 % relative humidity; grades with low residual free barium chloride exhibit no surface exudation. In comparison with C.I. Pigment Red 48:2, the BBC-Y grade demonstrates more yellow hue but lower heat aging stability above 150 °C; this restricts its use in EPDM compounds requiring continuous service above that threshold. Processors should verify lot-specific residual soluble salts by ISO 787-3 or ISO 787-4 before use in rubber.
Thermosetting polyester/epoxy powder coating extrusion at 90–110 °C barrel temperature and 5–10 kW twin-screw kneader loading uses the pigment at 0.5–2.5 wt%. The lower processing temperature avoids lake decomposition but requires pre-milling to reduce agglomerates. The pigment's heat stability in powder coatings is limited by cure cycles above 180 °C; extended cure at 200 °C for 10 min produces hue shift and gloss reduction. The grade differs from quinacridone red pigments in heat and light stability profile rather than in hue. Published data for this specific configuration is limited; a full factorial bake schedule is recommended for each powder coating system.
Flexible PVC calendering at 150–170 °C uses the grade in semi-rigid film; migration resistance in plasticized PVC is evaluated after 24 h contact with white PVC under 5 kPa load at 70 °C according to DIN EN 14469-3. The fast scarlet grade exhibits moderate migration; therefore use in soft PVC with high plasticizer content above 30 phr dioctyl phthalate is limited to light-tint applications or short service life. This limitation contrasts with high-performance organic reds that show no migration under identical conditions. Solvent bleeding in PVC plastisol is assessed by 24 h extraction in 100 % dioctyl phthalate at 150 °C; residual colour in the plasticizer is visually compared against a control. Such tests should be repeated for each plasticizer because migration rate scales with plasticizer solvency parameter.
Regulatory status is batch- and region-dependent and must be confirmed against the supplier safety data sheet and analytical declaration. The pigment is subject to REACH registration obligations; heavy-metal release for toy applications should be assessed according to EN 71-3 or ASTM F963-17. RoHS screening for lead, cadmium, mercury, and hexavalent chromium follows IEC 62321-5 and IEC 62321-4. For direct food-contact polymer use, no blanket approval is imputed from the Colour Index designation; migration testing under EU 10/2011 or FDA 21 CFR 177 conditions is required. Published data for this specific configuration is limited; the values in the following table represent a compliance checklist rather than a certification.
| Standard/regulation | Analyte or restriction | Method/limit | Required action |
|---|---|---|---|
| REACH Annex XVII entry 63 | lead in paint | ≤90 mg/kg dry film | Lot-specific declaration |
| EN 71-3:2019+A1:2021 | barium, lead, cadmium, chromium migration | limits by toy material category; extraction per EN 71-3 | Third-party test |
| ASTM F963-17 clause 4.3.5 | soluble heavy metals in toy substrate | limits per substrate; extraction per ASTM F963-17 | Third-party test |
| IEC 62321-5:2013 | lead | ≤1000 mg/kg homogeneous material | XRF screening |
| IEC 62321-4:2013 | mercury | ≤1000 mg/kg homogeneous material | XRF screening |