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Lithol Rubine 4BGL

    • Product Name: Lithol Rubine 4BGL
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales3@liwei-chem.com
    • Manufacturer: Nanjing Color Science Co.,Ltd
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    Specifications
    HS Code 573217
    Productname Lithol Rubine 4BGL
    Colorindexname Pigment Red 57:1
    Colorindexnumber CI 15850:1
    Casregistrynumber 5281-04-9
    Ecnumber 226-102-7
    Chemicalclass Monoazo calcium salt
    Molecularformula C18H12CaN2O6S
    Molecularweight 424.44 g/mol
    Physicalform Powder
    Colorshade Bluish red
    Specificgravity Approximately 1.8 g/cm³
    Oilabsorption Approximately 40-50 g/100 g
    Ph Approximately 6-8
    Moisturecontent ≤1.0%
    Watersolublematter ≤1.0%
    Lightfastness Approximately 4 on blue wool scale
    Heatstability Typically stable up to 180 °C
    Acidresistance Good
    Alkaliresistance Good
    Solventresistance Good
    Migrationresistance Good
    Typicalapplications Offset inks, packaging inks, paints, and plastics

    As an accredited Lithol Rubine 4BGL factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Lithol Rubine 4BGL is supplied in 25 kg multiwall paper sacks with polyethylene liners, palletized for industrial handling.
    Container Loading (20′ FCL) Lithol Rubine 4BGL is loaded into a 20-foot FCL container in securely palletized, moisture-protected packaging suitable for safe ocean transport.
    Shipping Lithol Rubine 4BGL is typically shipped as a non-hazardous pigment in sealed, labeled bags or fiber drums. Keep packages dry, clean, and protected from moisture and sunlight. No special transport classification generally applies; verify the current SDS, carrier requirements, and local regulations before shipment.
    Storage Store Lithol Rubine 4BGL in a cool, dry, well-ventilated area away from direct sunlight, heat, ignition sources, and incompatible materials such as strong oxidizers and acids. Keep containers tightly closed, properly labeled, and off the floor. Avoid dust generation and moisture contact; use appropriate grounding and local exhaust when handling. Maintain good housekeeping and spill control.
    Shelf Life Typical shelf life is 5 years when stored in original, unopened packaging under dry, cool, well-ventilated conditions away from direct sunlight.
    Application of Lithol Rubine 4BGL

    At Which Pigment Loading Does PR57:1 Reach Colouristic Parity with PR122 in Offset Magenta?

    The use of PR57:1 in sheetfed offset magenta ink is constrained less by mass tone than by fastness and transparency requirements set out in ISO 2846-1:2017. In commercial sheetfed and coldset offset magenta concentrates, the pigment loading is normally set between 15 wt% and 25 wt% in the finished ink because the calcium-laked monoazo pigment produces a high-tint-strength bluish magenta but cannot match the solvent resistance and lightfastness of high-performance alternatives such as PR122. Direct colouristic parity with PR122 is not achieved at equal loading, and formulators usually raise the PR57:1 loading to approach PR122 mass tone while accepting lower fastness. Relevant compliance references for general industrial sheetfed work include ISO 2846-1:2017 for process magenta colour and transparency, ISO 12647-2:2013 for pressroom control, and REACH (EC) No 1907/2006 for substance registration. Production-scale milling is carried out on a three-roll mill with hydraulic roll pressure and cold water cooling because the high-viscosity lithographic vehicle, typically a rosin-modified phenolic and alkyd system with linseed oil, generates shear heating that can damage the azo lake. Particle-size control is critical because residual aggregates above 15 µm cause piling on the blanket, ink-water emulsification instability, and plate wear on multi-unit sheetfed presses. The ink is generally passed through the three-roll mill until the grind gauge reading is ≤ 15 µm; in-process tack measured on an Inkometer at 30 °C is typically held between 10 and 14 Inkometer units, although published data for commercial magenta tack varies by ink house. Raw pigment receipt control for PR57:1 is usually performed against the matrix below before the pigment is released into the dispersion area. The values shown are consensus acceptance bands derived from material specifications rather than universal limits.

    Raw pigment control matrix for PR57:1
    ParameterTest methodTypical acceptance band
    Water-soluble matter, hot extractionISO 787-3:2000≤ 1.0%
    Oil absorptionISO 787-5:198040–60 g/100 g
    Aqueous suspension pHISO 787-9:20196.0–8.0
    Residue on 45 µm sieveISO 787-7:2009≤ 0.5%

    The terminal products for PR57:1 in offset inks are commercial sheetfed print, folding carton board, publication covers, and non-direct-food packaging. When direct food contact is implied, the formulator should not rely on generic PR57:1 compliance statements because published migration data for this specific configuration is limited; the finished printed article must be tested under the applicable national or EU food-contact regulation. The pigment is not intrinsically low-migration, and the use of PR57:1 in direct food-contact packaging should be avoided unless the finished structure provides a functional barrier.

    Solvent-Borne Lamination Ink Formulation for PR57:1 and Nitrocellulose-PU Systems

    Published gravure and flexographic ink formulations based on PR57:1 typically disperse the pigment at a loading of 6–12 wt% in a solvent blend containing ethyl acetate and isopropanol or ethanol, with nitrocellulose and a polyurethane or PVB resin as the film-forming portion. The pigment is first pre-wet with a low-molecular-weight dispersant in the solvent blend in a high-speed dissolver, then transferred to a horizontal bead mill charged with 0.8–1.2 mm zirconia beads. Grinding chamber temperature is maintained below 40 °C because the azo lake can undergo recrystallization and colour drift when solvent temperature rises excessively. Flow time after let-down is adjusted with a DIN 4 mm cup to between 18 s and 25 s for gravure and between 22 s and 30 s for flexographic presses; the same pigment may require different solvent-retention profiles on high-speed flexo decks. Experience on production laminating lines shows that insufficient polyurethane content causes de-inking or colour bleed into the adhesive layer at laminating nip temperatures above 60 °C, while excess nitrocellulose hardens the ink film and reduces bond strength. Compliance under the EU packaging ink framework requires good manufacturing practice under EC No 2023/2006 and EuPIA GMP, with REACH registration under (EC) No 1907/2006. The terminal products are surface-printed and laminated flexible packaging films such as OPP, PET, and polyamide, as well as labels and shrink sleeves. PR57:1 is not recommended for retort packaging, direct food-contact surfaces, or high-temperature ovenable laminates because the pigment has limited solvent fastness and low-molecular-weight dye components can migrate under abuse conditions; published migration data for those structures is limited and must be generated on the final package.

    Calendering plasticised PVC floor tile stock containing PR57:1 requires pre-dispersion of the pigment in a plasticiser paste before the dry blend reaches the calender rolls. In flexible PVC, PR57:1 is added at 0.5–2.0 phr; in rigid PVC profile and sheet extrusion, the loading is usually reduced to 0.2–1.0 phr because higher loadings contribute to plate-out and surface defects at the calender. The pigment is first mixed with dioctyl phthalate or another plasticiser in a high-speed dissolver or sigma-blade mixer to form a 30–40% pigment paste, then this paste is incorporated into the PVC dry blend in a high-speed mixer heated to 80–100 °C. The compound is fluxed on a two-roll mill at 150–160 °C and calendered at roll temperatures between 160 °C and 180 °C. Process temperature above 200 °C produces measurable colour strength loss and a shift toward yellow-red due to thermal degradation of the azo chromophore, so residence time at the upper temperature boundary is kept to the minimum needed for gelling. Production-scale floor tile and coated fabric lines observe plate-out on the calender roll surface when the pigment paste is not fully infiltrated by plasticiser or when the mill gap is opened too quickly; the defect appears as a dull deposit that transfers to the finished sheet edge. Compliance for toy-grade flexible PVC is assessed by extraction testing under EN 71-3:2019+A1:2021, and general PVC articles placed on the EU market require REACH (EC) No 1907/2006 registration. Terminal products include calendered vinyl floor tile, wall-covering sheet, coated fabric for upholstery, and toy-grade soft PVC sheets. Outdoor use is not recommended for PR57:1-coloured flexible PVC because the pigment exhibits moderate lightfastness and will fade faster than diarylide or DPP alternatives; if outdoor service is required, accelerated weathering under ISO 4892-2:2013 should be performed on the finished article.

    For polypropylene caps and high-density polyethylene closures coloured with PR57:1 masterbatch, the let-down ratio is normally determined by the pigment’s upper processing temperature rather than by dispersion difficulty. Masterbatch producers manufacture PR57:1-loaded PP or PE masterbatch at 20–35 wt% pigment using a co-rotating twin-screw extruder with an L/D ratio of at least 40:1. The screw profile is configured with kneading blocks after the pigment feed zone to break up agglomerates, while the melt temperature is held between 180 °C and 200 °C. A melt temperature above 220 °C during compounding results in pressure rise at the screen pack and a detectable loss of colour strength, which is observed as an increased let-down ratio required to match the colour standard on the injection moulding machine. At the injection moulder, the masterbatch is blended at 2–4 wt% into the natural polymer to give a final PR57:1 loading of 0.4–1.2 wt%. Regulatory status for polyolefin articles is established through REACH (EC) No 1907/2006, Directive 2011/65/EU RoHS where electrical and electronic housings are involved, and EN 71-3:2019+A1:2021 for toy articles; food-contact mouldings should not be assumed compliant unless finished-article migration is tested under the relevant plastics regulation. Terminal products include PP caps, HDPE closures, polypropylene housewares, cosmetic packaging, and rigid toy components. The use of PR57:1 in outdoor polyolefin furniture or automotive exterior parts is not recommended because the moderate lightfastness of the pigment cannot maintain colour within usual automotive exterior ΔE limits; published data for PR57:1 in long-term outdoor PP is limited.

    When Sulphur-Cured Elastomers Require a Magenta Shade Without Cadmium Pigments

    Natural rubber and styrene-butadiene rubber compounds coloured with PR57:1 are usually mixed in a Banbury internal mixer with a batch size calculated on the mixer chamber volume, because the pigment must be dispersed into the rubber phase before sulphur crosslinking locks in the morphology. PR57:1 is added at 0.5–1.5 phr in coloured rubber compounds; higher loadings above 2.0 phr may cause migration to the surface and a bloom-like deposit on finished goods. The Banbury is operated at a rotor speed of 30–50 min⁻¹, and the drop batch temperature is kept below 130 °C to avoid premature scorch and pigment degradation. The batch is sheeted out on a two-roll mill at 40–60 °C before the sulphur and accelerator are added in the final mixing stage. Vulcanisation is carried out in a hydraulic press at 150–160 °C for 8–12 min depending on section thickness; PR57:1 remains stable under these cure conditions. Mixing control and test-sheet preparation follow ASTM D3182-21, and the colour of moulded plaques can be measured with a spectrophotometer using D65/10° geometry. Compliance references for rubber goods are REACH (EC) No 1907/2006 and, where applicable, EN 71-3:2019+A1:2021 for toy and childcare articles. Terminal products include shoe soling sheet, indoor rubber mats, extruded sealing profiles for interior duty, and coloured rubber components in household appliances. Outdoor rubber profiles and automotive weatherstrip are not appropriate for PR57:1 because the pigment’s moderate lightfastness causes visible fading; if outdoor use is required, accelerated weathering must be run on the specific compound.

    Because PR57:1 is used in moderate-lightfastness artist and educational paints, the dispersion step determines whether finished poster colours and markers pass heavy-metal extraction limits and retain acceptable colour strength after shelf storage. The finished water-based poster paint or drawing ink typically contains 4–8 wt% PR57:1; concentrated pigment preparations for paint factories are produced at 30–40 wt% pigment with a wetting agent and a humectant such as propylene glycol. The dispersion is prepared in a high-speed dissolver for pre-wetting, then passed through a horizontal bead mill charged with 0.6–1.0 mm ceramic beads. Milling temperature is held below 35 °C because prolonged high-temperature processing increases foam and can shift the hue of the dispersed azo lake. The millbase is filtered through a 10 µm bag filter before tinting and filling. Safety labelling and chronic hazard evaluation for artist materials follow ASTM D4236-23; children’s poster paints and markers sold in the EU are tested for soluble heavy metals under EN 71-3:2019+A1:2021, and the pigment itself must comply with REACH (EC) No 1907/2006. Terminal products include poster paints, school water-based markers, drawing inks, and stamp-pad inks. PR57:1 is not recommended for fine-art permanent paintings or outdoor murals because its lightfastness, generally rated at Blue Wool Scale 4 with ISO 105-B02, would cause colour loss within a relatively short service period; artists’ material manufacturers should label such products accordingly under ASTM D4236-23.

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    Certification & Compliance
    More Introduction

    Lithol Rubine 4BGL is a commercial grade of the calcium salt of 3-hydroxy-4-[(4-methyl-2-sulfonatophenyl)diazenyl]-2-naphthoic acid, listed as C.I. Pigment Red 57:1 with CAS Registry Number 5281-04-9. The pigment belongs to the monoazo red lake class and is supplied primarily as a low-dust powder, granular compact, or presscake; the 4BGL designation identifies a blue-shade masstone with controlled rosin modification for rheology and gloss stability in paste ink systems. The chromophore is formed by diazotization of 2-amino-5-methylbenzenesulfonic acid and coupling with 2-hydroxy-3-naphthoic acid, followed by laking with calcium chloride and co-precipitation with calcium rosinate. The finishing step determines primary aggregate size distribution, specific surface area, oil absorption, and dispersibility in non-polar vehicle systems.

    Grade-level specification for 4BGL requires batch-to-batch control of mass color, tint strength, oil absorption, pH, moisture, and sieve residue. Mass color and tint strength are evaluated under ISO 787-1:1982 and ISO 787-25:1993 against an internal master standard; color differences are expressed in CIELAB units under ISO 11664-4:2008. Oil absorption is determined by ISO 787-5:1980 and typically falls within the general PR 57:1 class range of 40–60 g/100 g; the 4BGL grade is adjusted to the lower portion of this range when high pigment loading in offset inks is required. Aqueous pH is measured by ISO 787-9:1981 and controlled between 6.5 and 8.5. Moisture content by loss on drying is held below 2.0 wt% to prevent bridging in dosing feeders and to limit hydrolysis of the calcium lake during extended storage.

    Parameter Method Control range / boundary
    Oil absorption ISO 787-5:1980 40–60 g/100 g class range; batch certificate required
    Aqueous suspension pH ISO 787-9:1981 6.5–8.5
    Moisture content Loss on drying at 105 °C ≤ 2.0 wt%
    Dispersion fineness in offset vehicle Hegman gauge 5–6 µm after three-roll milling
    Bleed resistance ISO 787-22:1980 adapted Low bleed in aliphatic hydrocarbons; limited in ethanol/water above 50 °C

    Particle Morphology, Dispersion Energy, and Plate-Out Tendencies

    Primary particles of PR 57:1 exist as small azo lake crystallites with dimensions below 0.2 µm, but the dry pigment consists of aggregates that must be broken in high-shear processing. The rosin content of 4BGL increases the critical shear stress for aggregate rupture in aliphatic hydrocarbon vehicles, meaning that a three-roll mill or an enclosed bead mill is required for full color development. In a typical sheet-fed offset ink, 4BGL is introduced into a phenolic-modified rosin ester vehicle at 18–22 wt%, pre-mixed by high-speed dissolver, and milled in three passes at hydraulic pressures of 0.6–1.2 MPa and roll temperatures held below 45 °C. Finished grind is monitored with a Hegman gauge and released at 5–6 µm or better; under-milling produces lower gloss and higher tinting strength variability because residual aggregates act as viscosity-building particles. Over-milling can generate fine particles that increase vehicle demand and may cause ink body to rise after storage.

    Dispersion energy requirements for 4BGL are lower than those for carbazole violet but higher than for diarylide yellows. In bead-milled liquid ink formulations, optimal color development occurs with 0.6–0.8 mm zirconium oxide beads at tip speeds of 10–14 m/s. The high surface area and calcium-rosin interface make the pigment sensitive to moisture during dispersion; water content above 0.3% in the millbase can shift the charge and produce foaming in solvent-based systems. On production-scale closed bead mills, foam generation increases internal pressure and reduces flow through the cooling jacket, requiring reduced throughput or temporary increase in defoamer concentration.

    Offset ink and solvent-based liquid ink applications place different demands on the crystal surface. In sheet-fed oxidation-dried inks, 4BGL is typically dispersed in a phenolic-modified rosin ester vehicle using a three-roll mill with roll temperatures held below 45 °C; overheating above 60 °C can accelerate vehicle bodying and shift tack. In solvent-based liquid inks, 4BGL is milled in a high-speed dissolver followed by bead milling with 0.6–1.0 mm zirconia media, with the grind checked by a Hegman gauge to NS 5 or finer. Resin selection must account for the pigment’s sensitivity to strong amine stabilizers; exposure to monoethanolamine at elevated concentration can strip calcium from the lake and reduce color strength through partial conversion to the free acid form.

    What Limits Solvent Fastness and Alkali Resistance in Calcium Lake Chemistry?

    The calcium lake structure of 4BGL provides adequate resistance to aliphatic and aromatic hydrocarbon swelling in offset ink vehicles, but polar solvents attack the ionic calcium–sulfonate bridge more rapidly than they affect covalent high-performance organics. Bleeding is assessed by contact with ethanol, ethyl acetate, methyl ethyl ketone, and toluene under conditions adapted from ISO 787-22:1980. In ethanol at 20 °C, the pigment shows low bleed in short-term exposure, but bleed ratings degrade as temperature rises above 40 °C or when water is added to the solvent. Methoxypropanol and ethanol/water mixtures above 50:50 volume ratio are particularly aggressive because they combine polar solvation of the sulfonate group with calcium ion exchange at the particle surface.

    Alkali resistance is a processing boundary for 4BGL. Contact with sodium hydroxide solution at concentrations as low as 0.5 wt% causes shade drift and partial de-laking within minutes at 25 °C. This property excludes the pigment from applications requiring retortable packaging, caustic cleaning, or prolonged contact with alkaline aqueous media. The same limitation affects water-based ink systems containing ammonia or high-pH amine dispersants; formulation pH should remain below 9.0 and preferably below 8.0 to preserve color strength and prevent soluble calcium species from destabilizing acrylic emulsions.

    Polyolefin masterbatch trials on a 44:1 L/D co-rotating twin-screw extruder illustrate the thermal boundary of 4BGL. When 4BGL is let down at 0.8 wt% in polypropylene homopolymer with melt flow index 12 g/10 min measured under ISO 1133-1:2022, full color strength develops without severe warping, but residence times above 3 min at melt temperatures above 230 °C produce measurable yellow shift and die-lip plate-out. The plate-out is attributed to decomposition of the rosin modification and release of calcium salts; it is controlled by increasing the purge interval, reducing screw fill, or switching to a low-rosin PR 57:1 grade. In high-density polyethylene blow-molding equipment with 20:1 L/D single-screw extruders, barrel temperatures above 240 °C cause noticeable color fade and occasional black specks from carbonized rosin. Published data for 4BGL in this specific configuration is limited, and pre-production validation runs are required.

    When 4BGL Replaces C.I. Pigment Red 48:2 in Thermoformed Polypropylene Sheet

    In polypropylene sheet extrusion, substitution of C.I. Pigment Red 48:2 with 4BGL changes both shade and processing tolerance. At equal pigment loading of 0.5 wt%, 4BGL produces a bluer red with higher chroma but lower opacity; the difference is quantified by CIELAB comparison under ISO 11664-4:2008 and manifests as lower b* values and a slight reduction in a* relative to PR 48:2 in 2 mm plaques. The reduction in opacity is due to finer primary crystal size and lower scattering coefficient; it requires adjustment of titanium dioxide from 0.5–1.5 wt% to maintain hiding power. Heat stability of PR 48:2 is superior by approximately 20 °C under repeated extrusion, so 4BGL is not a direct drop-in replacement when regrind levels exceed 15 wt% or when melt temperature exceeds 220 °C. Migration fastness of 4BGL in polypropylene is inferior to PR 48:2; contact with plasticized PVC or ABS under pressure at 60 °C for 72 h can cause visible staining.

    Solvent-based decorative coatings represent a secondary use. In nitrocellulose furniture lacquers and alkyd metal paints, 4BGL is dispersed in short-oil alkyd or acrylic vehicles at 10–15 wt% based on binder solids. The blue-shade red mass tone permits shading of mid-reds without the cost of quinacridone. However, the pigment has limited lightfastness in pale tint; full-shade coatings show acceptable indoor performance but are not specified for exterior exposure. In baking enamels, crosslinker type and pH influence shade; acid-catalyzed melamine systems can produce a slight yellow shift when cure schedules exceed 140 °C for 20 min.

    Relative to other monoazo red lakes, 4BGL occupies a narrow position. Compared with C.I. Pigment Red 53:1, it is significantly bluer and weaker in alkali resistance but stronger in tinctorial value in sheet-fed ink. Compared with C.I. Pigment Red 48:2, it offers superior blue-shade cleanliness but lower heat resistance and higher bleed in aromatic solvents. Compared with the unlaked sodium salt C.I. Pigment Red 57, the calcium lake has improved water resistance and vehicle compatibility. In high-performance applications requiring 1,000 h exterior durability or continuous service above 260 °C, grades based on C.I. Pigment Red 122 or C.I. Pigment Red 254 are substituted, though at higher raw material cost and lower tinctorial strength per unit cost.

    Regulatory review of 4BGL must account for the calcium lake and sulfonated aromatic chemistry. Under EU Directive 2011/65/EU (RoHS) Annex II, lead, cadmium, mercury, and hexavalent chromium are restricted at homogeneous-material thresholds; pigment lots require batch-certified heavy metal data below the specified maximum concentration values. Under REACH, the substance is subject to safety data sheet classification for hazardous decomposition products and relevant registration obligations. Users should verify the presence of any specific migration limits under EU 10/2011 before using the pigment in food-contact plastics; PR 57:1 is not generally assigned a specific migration limit and may require demonstration that total migration and non-intentionally added substances comply with Articles 19 and 20.