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Fast Scarlet 2BN

    • Product Name: Fast Scarlet 2BN
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales3@liwei-chem.com
    • Manufacturer: Nanjing Color Science Co.,Ltd
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    Specifications
    HS Code 609734
    Productname Fast Scarlet 2BN
    Synonyms Sudan IV; C.I. Solvent Red 24; C.I. 26105; Sudan Red IV; Scarlet Red; Oil Red IV
    Chemicalname 1-[[2-Methyl-4-[(2-methylphenyl)azo]phenyl]azo]-2-naphthalenol
    Chemicalclass Azo dye
    Molecularformula C24H20N4O
    Molecularweight 380.44 g/mol
    Casregistrynumber 7023-61-2
    Ecnumber 201-635-8
    Colourindexname Solvent Red 24
    Colourindexnumber 26105
    Appearance Dark red to brownish-red powder
    Meltingpoint 199-204 °C
    Watersolubility Insoluble in water
    Organicsolventsolubility Soluble in chloroform, ethanol, acetone, oils, and fats
    Primaryuse Biological lipid stain and fat-soluble dye

    As an accredited Fast Scarlet 2BN factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Fast Scarlet 2BN is packaged in 25 kg net woven plastic bags with inner polyethylene liners for safe handling and storage.
    Container Loading (20′ FCL) Fast Scarlet 2BN is packed in suitable drums and loaded into a 20-foot FCL container, secured for safe export transport.
    Shipping Ship Fast Scarlet 2BN in tightly closed, labeled containers in a cool, dry, well-ventilated area. Protect from moisture, heat, direct sunlight, and physical damage. Avoid dust generation. Verify the SDS and applicable transport regulations; unless classified as dangerous goods, it is normally shipped as non-hazardous. Follow carrier and local requirements.
    Storage Store Fast Scarlet 2BN in a cool, dry, well-ventilated area, protected from direct sunlight, heat, moisture, and ignition sources. Keep containers tightly closed, clearly labeled, and separated from strong oxidizers and incompatible materials. Avoid dust generation, provide local exhaust if needed, use appropriate PPE, and follow the supplier’s SDS and local regulations.
    Shelf Life Fast Scarlet 2BN has a typical shelf life of about two years when stored cool, dry, and away from light in sealed containers.
    Application of Fast Scarlet 2BN

    Fast Scarlet 2BN is handled in the following application set as a red azo pigment of the carboxylated β-naphthol lake class; the Colour Index designation should be confirmed against the supplier lot because the trade name itself is not a Colour Index identifier and may correspond to C.I. Pigment Red 48:2 in some industrial formulations. The downselection to six downstream matrices is limited to established mill-scale uses for azo scarlet pigments of this type. In each matrix, the four required data classes—regulatory boundary, formulation loading, production process sequence, and terminal article type—are reported with the equipment type or test method that constrains the claim. Where a numerical operating band is not available from a cited method, lot-specific validation is stated as the controlling requirement instead of supplying an unverifiable figure. None of the values below replace a bound technical datasheet, migration report, or production trial.

    In solventborne flexographic and gravure surface ink compounding, the pigment is introduced into the resin cut rather than added as dry powder at the press. A typical nitrocellulose-polyurethane ink is processed with a saw-tooth high-speed disperser at peripheral tip speeds of 18–25 m/s for 15–20 min, followed by horizontal bead milling with 0.8–1.2 mm yttria-stabilized zirconia beads until the fineness of grind measured per ISO 1524:2020 reaches 8–12 µm. The loading for high-strength scarlet ink is 10–14 wt% of total liquid ink for flexo surface printing; for gravure lamination reds where the ink film is reduced by adhesive lamination, formulating at 14–18 wt% is applied only after confirming that tack rise measured per ASTM D4361-10 remains within the press window. The milled base is let down with an ethyl acetate/n-propanol solvent blend to a final viscosity of 300–800 mPa·s at 25°C using a rotational viscometer per ASTM D2196-20. Terminal article types include surface-printed snack bags, non-food shrink sleeve film, industrial wrapper films, and pressure-sensitive label face stock. For food-contact printed matter, migration testing under Swiss Ordinance SR 817.023.21 and compliance with EU Directive 94/62/EC packaging heavy-metal limits are required unless a functional barrier is demonstrated. Light fastness should be screened according to ISO 2836:2021 because surface-printed packaging without overprint varnish can show shade fade if the supplied lot is below the print buyer’s specification.

    Where polyolefin compounders use Fast Scarlet 2BN in a high-colour-strength masterbatch for injection moulding, the development path is determined by dispersive shear and melt-temperature residence time rather than by tinting strength alone. The masterbatch is compounded at 30–45 wt% pigment in a low-density polyethylene or polypropylene carrier resin, and final letdown in moulded parts is controlled to 1.0–2.5 wt% for bulk colour, with 0.5–1.0 wt% used in thin-wall closures and bottles where excessive pigment loading increases warpage and dimensional shrinkage. Processing is conducted on a co-rotating twin-screw extruder with L/D 40:1 or L/D 44:1, screw speed 400–600 rpm, and melt temperature held below 220°C for calcium lake grades; above 240°C shade drift and strength loss become more probable, although published data for this specific configuration is limited and must be confirmed by a lot-specific thermal stability trial in the target resin. The pelletized masterbatch is let down on an injection moulding machine with melt temperature at 200–225°C and back pressure 5–10 bar to maintain colour stability. Terminal articles include homopolymer PP appliance housings, HDPE caps and closures, low-density polyethylene toys, and non-food cosmetic packaging components. Compliance is governed by FDA 21 CFR 178.3297 for polymer colorants when the end article may contact food, by EU Regulation (EU) No 10/2011 with batch migration testing for plastic food-contact materials, and by EN 71-3:2019+A1:2021 for toy migration limits; if the pigment batch contains banned aromatic amines above 30 ppm as determined by EN 14362-1:2017, the lot is not suitable for EU consumer goods.

    Compliance checklist for Fast Scarlet 2BN in non-food and food-contact downstream matrices
    Compliance domainStandard or regulationBatch release criterionTest method designation
    Packaging heavy metalsEU Directive 94/62/ECSum of Pb+Cd+Hg+Cr(VI) below 100 ppmEN 71-3:2019+A1:2021 digestion
    Azo colorant restrictionREACH Regulation (EC) No 1907/2006 Annex XVII entry 43Banned aromatic amines below 30 ppmEN 14362-1:2017
    Plastic food-contact materialsEU Regulation (EU) No 10/2011Pigment-specific migration limit or non-detect in food simulantEN 1186-1:2002
    Polymer colorants for food contactFDA 21 CFR 178.3297Lot-specific migration within 21 CFR thresholdFDA chemistry guidance total migration
    Toy migrationEN 71-3:2019+A1:2021Annex II metal release limitsEN 71-3:2019+A1:2021
    Print light fastnessISO 2836:2021Grade per buyer specificationISO 105-B02:2014

    Rubber Vulcanization Rates when Fast Scarlet 2BN Is Predispersed in a Carrier Binder

    Compression-moulded SBR and EPDM compounds show measurable cure shifts when Fast Scarlet 2BN is added as a predispersed paste, especially if the supplied powder contains residual soluble metal salts. The pigment is incorporated at 1.0–3.0 phr, preferably as a 40–50 wt% predispersed paste in a rubber-compatible carrier or as a dust-suppressed granular grade to avoid stratification in internal mixers. Mixing is carried out in a Banbury or intermeshing internal mixer with a drop temperature of 110–120°C, followed by two-roll mill finishing at 70–90°C; accelerators and sulfur are added in the final phase to avoid scorch. Cure behaviour is measured on an oscillating disc curemeter per ISO 6502-1:2018 or ISO 3417:2018 at 160–170°C, and standard mix preparation is documented per ISO 2393:2017. Terminal products include SBR footwear soles, EPDM roofing membrane edges, NBR hose covers, and solid rubber industrial mats. The operational boundary is the interaction with acidic accelerator systems; if scorch time measured as ts2 under ISO 6502-1:2018 drops below 1.5 min at production temperature, the pigment batch should be checked for pH and soluble metal content per ISO 787-9:2019 before scale-up.

    Compliance for rubber articles is driven by final use category: footwear sold in the EU must meet PAH limits in REACH Regulation (EC) No 1907/2006, Annex XVII entry 50, and industrial rubber goods require heavy-metal release data if supplied to automotive OEMs. Fast Scarlet 2BN lots should be screened for polycyclic aromatic hydrocarbons per ISO/TS 16190:2013 and for lead and cadmium by atomic absorption following acid digestion. Because the pigment is not reinforcing, it should not be used above 3.0 phr in dynamic applications where tensile strength and tear resistance are critical; higher loadings may reduce elongation at break, and the loss should be quantified per ASTM D412-16 on the production batch.

    What Limits Pigment Volume Concentration in Waterborne Architectural Coatings?

    Because waterborne acrylic and styrene-acrylic architectural coatings operate at high pigment volume concentration, the pigment must remain wetted in a high-water system without excessive surfactant migration. Fast Scarlet 2BN is added at 2.0–5.0 wt% of total liquid coating for deep red wall paints and 1.0–2.0 wt% for pastel base tints, with the lower end preferred when volumetric tinting machines are used to avoid nozzle blocking. The pigment is predispersed in a high-speed disperser with a tip speed of 15–20 m/s for 10–15 min, then ground in a redox-stable acrylic or styrene-acrylic mill base to a Hegman grind of 6–7 measured per ASTM D1210-05 or ISO 1524:2020. The final coating viscosity is typically adjusted to 90–110 KU at 25°C using a Stormer viscometer per ASTM D562-10. Terminal types include low-VOC interior wall paints, waterborne masonry finishes, and red decorative topcoats for plaster and gypsum. Compliance is anchored to EU Directive 2004/42/EC VOC limits for paints and varnishes and to ASTM D2244-23 for instrumental colour difference; exterior grades require accelerated weathering under ISO 16474-2:2013 to document red-pigment fade before an exterior warranty is assigned.

    The critical pigment volume concentration boundary is set by the supplier-reported oil absorption value measured per ISO 787-5:1980. High-PVC flat formulations above 55% PVC may show scrub resistance loss and burnishing because the pigment competes with binder solids at reduced binder demand. A batch-specific CPVC calculation is therefore required before reducing binder content; a viscosity recovery test after 24 h at 25°C using ASTM D2196-20 should show less than 10% increase to confirm colloid stability.

    Dry Blend Homogeneity and Particle Size Control in Thermoset Powder Coating Extrusion

    Thermosetting polyester-epoxy hybrid powder coating manufacture requires Fast Scarlet 2BN to be pre-blended into the dry mix before melt extrusion rather than introduced downstream. The addition ratio is 1.5–4.0 wt% of total powder formulation for full red shades and 0.8–1.2 wt% for tinted pink or terracotta products. Dry blending is performed in a high-intensity mixer at 600–900 rpm for 3–5 min to achieve homogeneous pigment distribution before the melt phase. The premix is extruded through a twin-screw extruder with barrel temperatures held in the narrow window of 95–105°C; the lower boundary is set by incomplete pigment wetting and the upper boundary by the onset of resin crosslinking, which can appear as gel particles in the final coating. The extrudate is chilled on a cooling roll, crushed, and ground through an air-classifying mill, with target particle size distribution controlled at 80–140 µm by sieve analysis per ISO 8130-2:2021. Terminal articles include metal office furniture, architectural aluminium extrusions, automotive interior brackets, and agricultural equipment housings. Compliance is controlled by ISO 8130-2:2021 for particle size distribution, ISO 8130-6:2021 for gel time of thermosetting powders, and ASTM D3359-17 adhesion rating after cure; heavy-metal limits for powder coatings are assessed under REACH Regulation (EC) No 1907/2006 restricted substances guidance.

    Moisture is a process conflict in this matrix. If the pigment powder is stored at relative humidity above 60% or in an unsealed hopper, adsorbed moisture can reduce electrostatic charging efficiency and cause spitting in the spray booth. A pre-drying step at 60–70°C for 2–4 h in a forced-air oven is required before dry blending when volatile content per ISO 787-2:1981 exceeds 0.5%. The process window of ±5°C around the 95–105°C barrel temperature is the critical control point; excursions above 110°C increase the risk of pigment shade drift and partial resin pre-cure, while excursions below 90°C create pigment agglomerates that survive grinding and appear as specks in electrostatic spraying.

    If Textile Pigment Printing Pastes Are Processed on Rotary Screens

    In rotary screen printing of cellulosic and polyester-cotton substrates, the paste formulation requires the pigment to be fully dispersed before the binder and thickener are added. Fast Scarlet 2BN is used at 1.0–3.0 wt% of the final paste, with 2.0–3.0 wt% reserved for deep red grounds and 1.0–1.5 wt% for light tints on white base cloth. The production sequence includes high-shear stirring of the pigment into water with a non-ionic dispersant, addition of a low-formaldehyde acrylic binder at 8–15 wt%, and incorporation of a synthetic thickener at 2–4 wt% to reach a print viscosity of 15,000–30,000 mPa·s at 25°C per ASTM D2196-20. The paste is printed through a rotary screen, dried at 110–130°C for 2–5 min, and cured at 150–160°C for 3–5 min to achieve wet-rub fastness. Terminal article types include printed T-shirt panels, cotton tote bags, polyester-cotton curtain fabrics, and light upholstery covers. Compliance for consumer textiles is governed by OEKO-TEX Standard 100 Annex 4 limit classes for heavy metals and aromatic amines, by REACH Regulation (EC) No 1907/2006 Annex XVII entry 43 for banned azo colourants, and by ISO 105-C10:2006 for washing fastness. The critical high-shear limitation occurs at the squeegee nip: if the pigment flocculates under shear, the shade moves yellow-red and the print loses chroma; a post-shear viscosity recovery check after 24 h should show a change of less than 10%, and the colour difference should be below 1.5 CIELAB units measured per ASTM D2244-23 before the paste is released to production.

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    Certification & Compliance
    More Introduction

    Fast Scarlet 2BN is a calcium lake monoazo pigment conforming to C.I. Pigment Red 48:2 and identified by CAS 7023-61-2. The product is produced by diazotization of 2-amino-4-chloro-5-methylbenzenesulfonic acid and coupling with 3-hydroxy-2-naphthoic acid (BONA), followed by precipitation with calcium ions. The resulting molecule has the formula C18H11CaClN2O6S and a molar mass of 458.88 g/mol. The masstone is a yellow-shade scarlet; titanium dioxide reduction shifts toward a clean red-pink. Fast Scarlet 2BN is supplied as a powder or granular preparation. The granular grade is intended for low-dust metering on extrusion lines, while the powder grade is used in high-shear ink dispersion. The physical specification windows in the table below are commercial tolerance ranges; lot-specific certificates of analysis remain the release reference for numerical acceptance.

    ParameterTypical rangeTest method
    Density1.55–1.65 g/cm³ISO 787-10:1993
    Oil absorption40–50 g/100 gISO 787-5:1980
    pH of aqueous extract6.5–7.5ISO 787-9:2019
    Residue on 45 µm sieve≤0.10 wt%ISO 787-7:2009
    Specific surface area (BET)20–30 m²/gISO 9277:2010
    Matter volatile at 105 °C≤1.0 wt%ISO 787-2:1985
    Heat stability in polyolefin220 °CEN 12877-1:2000

    Because the density range is 1.55–1.65 g/cm³, a gravure ink concentrate formulated with 20 wt% pigment has a volumetric loading that differs from barium-analogue grades; when substituting C.I. Pigment Red 48:1, formulators convert by weight rather than by volume. The oil absorption range of 40–50 g/100 g corresponds to moderate binder demand. Higher values in a specific lot indicate finer particle size or increased surface area and will increase mill-base viscosity.

    What Distinguishes Fast Scarlet 2BN from Barium and Strontium Grades of PR48?

    In organic pigment applications, the choice of laking cation is a primary variable. The calcium salt in Fast Scarlet 2BN yields a lower density than the barium salt C.I. Pigment Red 48:1, and the crystal density changes volumetric dosing calculations in ink concentrates. Barium-containing C.I. Pigment Red 48:1 tends to a neutral red and can show higher tack build in lithographic vehicles at equal pigment volume concentration. The strontium salt C.I. Pigment Red 48:3 is bluer and is used for higher heat exposure in engineering resins. The calcium salt also has lower molar mass than the strontium salt, but direct comparative migration data for finished articles is limited. Differences among the PR48 metal salts are summarised below; values are typical commercial ranges from pigment manufacturers, not absolute product constants.

    GradeCationMasstone directionTypical heat stabilityTypical densityPrimary process use
    C.I. Pigment Red 48:1Ba²⁺neutral red250 °C1.75–1.85 g/cm³sheetfed offset inks, PVC plastisols
    C.I. Pigment Red 48:2Ca²⁺yellow-shade scarlet220 °C1.55–1.65 g/cm³gravure inks, decorative plastics, water-based flexo
    C.I. Pigment Red 48:3Sr²⁺blue-shade red260 °C1.75–1.85 g/cm³high-heat polyolefin masterbatch, engineering resins

    Relative to C.I. Pigment Red 57:1, Fast Scarlet 2BN contains chlorine and methyl substituents on the diazo component. These substituents lower solubility in alcohol-based flexo vehicles and shift the masstone from magenta to scarlet. C.I. Pigment Red 57:1 remains a bluer rubine with lower solvent resistance in certain nitrocellulose systems; Fast Scarlet 2BN is therefore specified when bleed resistance in alcohol-containing laminating adhesives is required. The difference is formulation-dependent; migration screening according to the intended laminate construction is required.

    In solvent-based toluene/nitrocellulose gravure ink concentrates, Fast Scarlet 2BN is dispersed on a high-speed dissolver with a peripheral speed of 18–25 m/s, then milled in a horizontal bead mill charged with 0.6–0.8 mm yttrium-stabilized zirconia media at 70–80% chamber loading. A fineness of grind below 5 µm under ISO 1524:2013 is typically obtained after two passes. At press speeds above 250 m/min, dispersion stability and low particle tail become critical; agglomerates larger than 5 µm cause streaking and cylinder wear. The pigment concentration in the letdown is balanced against the oil absorption value of 40–50 g/100 g because excessive loading raises tack and misting in high-speed units. The specification for residual solvent in the printed film is outside the scope of the pigment data sheet and is governed by converter-specific gravure drying conditions.

    When Processing Temperatures Exceed 220 °C in Polyolefin Masterbatch

    In high-speed compounding, the thermal history of Fast Scarlet 2BN controls final shade. On a twin-screw extruder with L/D 36:1 to 44:1, the pigment should be added through a side feeder located after the polymer melting zone; this limits residence time at melt temperature to 40–60 s. If the pigment is pre-blended in the main feed, the full melting zone residence time may exceed 90 s, and shade drift becomes measurable at barrel temperatures above 210 °C. The calcium lake undergoes particle ripening and demetallation at elevated temperature; the result is a brown shift and loss of chroma in injection-moulded plaques. A screening plaque is prepared according to EN 12877-1:2000 with a hold time of 10 min at 220 °C. If the target process temperature is 240 °C or higher, the strontium grade C.I. Pigment Red 48:3 or a higher-performance organic red is recommended. Published data for this specific configuration is limited for film-grade polypropylenes with melt temperature above 230 °C.

    Material exposed to relative humidity above 60% should be pre-dried at 70–80 °C for 2–4 h in a desiccant dryer with dew point below -20 °C before introduction into the extruder; residual moisture is measured by ISO 787-2:1985. Avoid melt blending with strong mineral acids or acidic fillers below pH 3.0; acidic conditions can strip calcium from the lake and generate dye acid migration. Avoid prolonged contact with strong reducing agents at high temperature; the azo linkage is stable below 220 °C but can undergo reductive cleavage in the presence of free radical initiators. These processing boundaries are specific to the lake structure and are not intended to override resin manufacturer safety limits.

    In water-based flexographic inks, Fast Scarlet 2BN is dispersed in an acrylic resin solution at pigment loadings from 30–40 wt%. The dispersion is processed on a bead mill with 0.4–0.6 mm ceramic media to a fineness below 5 µm. The letdown pH is held between 8.5–9.5; when pH falls below 8.0, the pigment suspension loses electrostatic stabilization and may flocculate in the anilox cells, producing lower transfer efficiency on the print deck. Sodium hydroxide is not recommended as the sole pH adjuster because local high pH above 10.0 can cause shade drift; volatile amines or ammonia are preferred. The pigment is characterized for aqueous paste viscosity on a Brookfield RVT viscometer at 20 rpm and 25 °C, with the target set by the press supplier. The viscosity target is not a universal specification because it depends on the dispersant polymer, pigment loading, and pH history.

    In air-drying alkyd decorative coatings, dispersion is carried out on a high-speed dissolver followed by a bead mill; the pigment loading in the mill base is set at 20–25 wt% to obtain a Hegman rating of 7–8 under ISO 1524:2013. The finished enamel is intended for indoor decorative use; exterior weathering is outside the recommended boundary because of the lightfastness ratings discussed below. In thermoset powder coatings based on carboxyl-functional polyester and triglycidyl isocyanurate, the extrusion premix is processed at 90–110 °C. Acid-functional polyester resins with acid values above 50 mg KOH/g may interact with the calcium lake; a gel time test after pigment dispersion is required to rule out catalytic side effects.

    Solvent Resistance, Migration, and Lightfastness Boundaries

    Fast Scarlet 2BN is insoluble in water and aliphatic hydrocarbons. Partial solubility may occur in polar aprotic solvents such as dimethylformamide and N-methylpyrrolidone; those solvents should not be used for extraction testing without documented recovery. In ethanol/ethyl acetate packaging gravure laminates, bleed resistance is formulation-dependent and must be confirmed by extraction testing in the intended adhesive and barrier construction. The pigment is stable in neutral and mildly alkaline aqueous media up to pH 10.0; below pH 3.0, calcium demetallation and shade drift occur. Full-shade lightfastness in air-drying alkyd is rated 5–6 on the blue wool scale under ISO 105-B02:2014; the 1:10 titanium dioxide reduction falls to 4–5. This limits Fast Scarlet 2BN to indoor decorative coatings, short-cycle labels, and packaging inks not exposed to continuous daylight. In plasticized PVC, migration resistance is typically rated 3–4 by manufacturer protocols based on ISO 105-A05:1996. Accelerated weathering under ISO 11341:2004 is not part of routine lot release, and published data for this specific configuration is limited; exterior use requires full exposure testing. The pigment is not recommended for exterior automotive topcoats or high-weathering coil coatings.

    Regulatory compliance must be established for the final article, not for the pigment as an isolated substance. Under EU REACH (EC 1907/2006), the registration dossier covers the monoazo lake and its manufacturing impurities. Elemental migration for toy safety is assessed by EN 71-3:2019+A1:2021 after acid extraction; barium and strontium traces are lot-dependent and are quantified by ICP-OES. Food-contact evaluations under EU Regulation 10/2011 or FDA 21 CFR 178.3297 require migration testing with food simulants representing the intended food type and polymer matrix. Published data for this specific configuration is limited for fatty-food simulants and high-temperature sterilization; a migration study on the final laminate or moulded article is required before use.